2-Methyl-3,5,6-triphenyl-2,3-dihydropyrazine

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2-Methyl-3,5,6-triphenyl-2,3-dihydro­pyrazine

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4-Methyl-2,4,6-triphenyl-4H-thio­pyran

The six-membered thio-pyran ring in the title compound, C(24)H(20)S, adopts a flattened boat conformation, with the S atom displaced by 0.273 (2) Å and the 3-methyl-ene C atom by 0.294 (3) Å from the plane of the other four sp(2)-hydridized C atoms. The methyl group on the methyl-ene carbon lies in a axial position with the phenyl equatorial.

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2-(4-Fluoro­phen­yl)-1,4,5-triphenyl-1H-imidazole

In the title mol-ecule, C(27)H(19)FN(2), the imidazole ring is essentially planar [maximum deviation = 0.004 (1) Å] and makes dihedral angles of 62.80 (6), 36.98 (6), 33.16 (6) and 46.24 (6)°, respectively, with the substituent rings in the 1-, 2-, 4- and 5-positions. No classical hydrogen bonds are observed in the crystal structure.

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2,4,5-Triphenyl-1,3,2-dioxa­phospho­lan-2-one

The dioxaphospho-lane ring in the title compound, C(20)H(17)O(3)P, adopts an envelope conformation about one of the ring carbons. The benzene rings of the compound do not form face-to-face π-π inter-actions, instead weak C-H⋯π inter-actions occur between adjacent mol-ecules. The methine H atoms on the dioxaphospho-lane ring form weak C-H⋯O hydrogen bonds to the oxide group of an adjacent mol-ec...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2009

ISSN: 1600-5368

DOI: 10.1107/s1600536809005042